Really very good, focuses on the political and social side more than Napoleon, though he still does feature heavily. I will certainly be getting more books from The Great Courses.
Do try this history of how Britain came to stand alone. The politics I expected, but of equal interest - and for me a little unexpected - was the recounting of the feelings and reactions of the Britsh people. The two threads combine to make compelling listening. Oh, and as well as not being able to win without the Americans, it was good to hear that without Britain the war would have been lost... and that from an American. Buy it.